Publications

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Book Chapters & Non Peer-Reviewed Articles

2. J.R. Pankhurst,* S. Hohloch*

"N-heterocyclic and mesoionic carbene complexes of the actinides"

Comprehensive Organometallic Chemistry IV, 2022, 201 - 206.

Link

1. L.J. Daumann*, S. Demir*, S. Hohloch*

“Trendberichte Bioanorganische und Koordinationschemie”

Nachr. Chem., 2019, 67, 65 - 80.

Link

Peer-Reviewed Publications

103. Stability and Catalytic Activity of 1,2,3-Triazolylidene Supported Dioxomolydenum and Dioxotungsten Complexes in the Catalytic Deoxygenation Reaction of Nitroarenes 

F.R. Neururer, F. Heim, P. Boos, S. Liu, M. Baltrun, J. Beerhues, S. Hohloch*

Inorg. Chem. Front., 2024, in preparation.

102. Facile Access to Highly Cytotoxic Metallocenium-Based Mesoionic Carbene Gold(I) Complexes via Fluorinative Desilylations

D. Menia, F. Neururer, K. Wurst, P. Lippmann, I. Esarev, I. Ott,* M. Podewitz,* S. Hohloch* and B. Bildstein*

Chem. Commun., 2024, in preparation.

101. Structural Doversity in Anilidophosphine Supported Lanthanide Chemistry

B. Wittwer, F. Hett, S.Hohloch*

Inorg. Chem., 2024, in preparation.

100. Neutral and Cationic Molybdenum and Tungsten Complexes Supported by a Tridentate PNP Ligand

D. Leitner, M. Henning, S. Hohloch*

Eur. J. Inorg. Chem. 2024, manuscript in preparation

99. Light induced splitting of P-C bonds in a lanthanum(III) phosphahemiketal complex

B. Wittwer, K.N. McCabe, D. Leitner, M. Seidl, L. Maron,* S.Hohloch*

Chem. Sci., 2024, 15, submitted.

98. Transferrin Receptor mediated Cellular Uptake of Fluorinated Chlorido[N,N´-bissalicylidene-phenylenediamine]iron(III) Complexes

A.D. Bernkop-Schnürch, M. Hermann, D. Leitner, S. Hohloch, R. Gust, B. Kircher* 

ACS Omega, 2024, under revision

97. Isostructural series of a cyclometalated iron complex in three oxidation states

J. Steube, L. Fritsch, A. Kruse, O. Bokareva, S. Demeshko, H. Elgabarty, R. Schoch, M. Alaraby, S. Hohloch, T.D. Kühne, F. Meyer, O. Kühn, S. Lochbrunner, M. Bauer*

Inorg. Chem. 2024, under revision.

96. Salene iron(III) complexes – Is increased lipophilicity key to enhanced cellular uptake?

A.D. Bernkop-Schnürch, K. Huber, A. Clauser, M. Cziferszky, D. Leitner, H. Talasz, M. Hermann, S. Hohloch, R. Gust, B. Kircher*

J. Med. Chem., 2024, submitted

95. A Versatile Comproportionation Route to construct mono-imido trichlorido precursors of molybdenum(V) and tungsten(V)

D. Leitner, K. Wurst, S. Hohloch*     

Z. Anorg. Allg. Chem., 2024, 650, e202300248.

DOI: 10.1002/zaac.202300248

Link

invited manuscript "Special issue Rhett Kempe"

94. A Mesoionic Carbene Stabilized Nickel(II) Hydroxide Complex: A Facile Precursor for C–H Activation Chemistry

A. Pavun, R. Niess, L.A. Scheibel, M. Seidl, S. Hohloch*

Dalton Trans., 2024, 53, 2749 - 2761.

DOI: 10.1039/D3DT03746K

Link

invited manuscript (by Editorial Office)

93. Scrutinising the Redox-Chemistry of Group 10 Complexes Supported by a Redox-Active bis-Phenolate Mesoionic Carbene

B. Wittwer, D. Leitner, F.R. Neururer, R. Schoch, M. Seidl, J. Pecak, M. Podewitz,* S.Hohloch*

Polyhedron, 2024, 250, 116786

DOI: 10.1016/j.poly.2023.116786

Link

Invited article for the special issue "Emerging Investigators"

92. Design, synthesis, electrochemical, and biological evaluation of fluorescent chlorido[N,N′-bis(methoxy/hydroxy)salicylidene-1,2-bis(4-methoxy-phenyl)ethylenediamine]iron(III) complexes as anticancer agents

A.D. Bernkop-Schnürch, D. Chavooshi, H. Descher, D. Leitner, H. Talasz, M. Hermann, K. Wurst, S. Hohloch, R. Gust,* B. Kircher*

J. Med. Chem., 2023, 66, 15916 - 15925.

DOI: 10.1021/acs.jmedchem.3c01359 

Link

91. Clathrochelate Complexes Containing Axial Cyamantrene and Tromancenium Moieties

R. Thaler, H. Kopacka, K. Wurst, T. Müller, F.R. Neururer, S. Hohloch, P. Lippmann, I. Ott,* B. Bildstein*

Eur. J. Inorg. Chem., 2023, e202300368

DOI: 10.1002/ejic.202300368 

Link

90. Expanding the Utility of Beta-Diketiminate Ligands in Heavy Group VI Chemisty of Molybdenum and Tungsten

D. Leitner, B. Wittwer, F.R. Neururer, M Seidl, F. Tambornino, S. Hohloch*

Organometallics, 2023, 42, 1411 - 1424.

DOI: 10.1021/acs.organomet.3c00056

Link

invited manuscript
special issue: Early Transition Metals in Organometallic Chemistry

89. The Chemistry of Vanadium bis-Phenolate NHC Complexes in Three Oxidation States

F.R. Neururer, D. Leitner, S. Liu, K. Wurst, H. Kopacka, M. Seidl, S. Hohloch*

Eur. J. Inorg. Chem., 2023, e202300180

DOI: 10.1002/ejic.202300180

Link

invited manuscript
special issues: NHC Ligands in Organometallic Chemistry and Catalysis

Front Cover Article
Pick of the week by Chemistry Europe

88. Curious Case of Cobaltocenium Carbaldehyde

D. Menia, M. Pittracher, H. Kopacka, K. Wurst, F.R. Neururer, D. Leitner, S. Hohloch, M. Podewitz,* B. Bildstein*

Organometallics, 2023, 42, 377 - 383.

DOI: 10.1021/acs.organomet.2c00613 

Link

87. Imidazolyl-substituted benzo- and naphthodithiophenes as precursors for the synthesis of open-shell quinoids

P. Hou, S. Peschtrich, W. Feuerstein, R. Schoch, S. Hohloch, F. Breher, J. Paradies*

ChemistryOpen, 2023, 12, e202300003

DOI: 10.1002/open.202300003 

Link

86. Janus-type emission of a Cyclometallated Iron(III) Complex

J. Steube, A. Kruse, O.S. Bokareva, T. Reuter, S. Demeshko, R. Schoch, M.A-Argüello Cordero, S. Hohloch, F. Meyer, K. Heinze, O. Kühn, S. Lochbrunner, M. Bauer*

Nature Chem., 2023, 15, 468 - 474. 

DOI: 10.1038/s41557-023-01137-w

Link

Preprint:  Link

85. Tromancenium Complexes with Steric and Electronic Modulation

A. Pavun, H. Kopacka, K. Wurst, T. Müller, F.R. Neururer, S. Hohloch,* B. Bildstein*

J. Organomet. Chem., 2023, 985, 122594

DOI: 10.1016/j.jorganchem.2022.122594
(invited manuscript, special issue ICOMC 2022)

Link

84. Reactivity and Structure of a bis-Phenolate Niobium-NHC Complex

F.R. Neururer, K. Huter, H. Kopacka, B. Wittwer, S. Hohloch*

ACS Org. Inorg. Au, 2023, 3, 59 - 71.

DOI: 10.1021/acsorginorgau.2c00028

Link

invited article (by Editorial Office)

83. Borylated Cymantrenes and Tromancenium Salts with Unusual Reactivity

R. Thaler, H. Kopacka, K. Wurst, T. Müller, D.F. Dinu, K.R. Liedl, F.R. Neururer, S. Hohloch, B. Bildstein*

Organometallics, 2022,  41,  1464 - 1473.

Link

82. A Mesoionic Carbene Complex of Manganese in Five Oxidation States

B. Wittwer, N. Dickmann, S. Berg, D. Leitner, L. Tesi, D. Hunger, R. Gratzl, J. van Slageren, N.I. Neumann,* D. Munz,* S. Hohloch*

Chem. Commun., 2022, 58, 6096 - 6099.

Link

81. Halogen-bonded Networks of Porous Organic Cages

E. Nieland, D. Komisarek, S. Hohloch, K. Wurst, V. Vasylyeva-Shor, O. Weingart,* B.M. Schmidt*

Chem. Commun., 2022, 58, 5233 - 5236.

Link

80. Coupling of CO2 and Epoxides Catalysed by Novel N-Fused Mesoionic Carbene Complexes of Nickel(II)

F.A. Watt, B. Sieland, N. Dickmann, R. Herbst-Irmer, H. Ott, R. Schoch, J. Paradies, D. Kuckling, S. Hohloch*

Dalton Trans., 2021, 50, 17361 - 17371.

Link

invited article

79. Mesoionic Carbenes in Low- to High-Valent Vanadium Chemistry

F. Neururer, S. Liu, D. Leitner, M. Baltrun, K.R. Fisher, H. Kopacka, K. Wurst, L.J. Daumann, D. Munz,* S. Hohloch*

Inorg. Chem., 2021, 60, 15421 - 15434.

Link

78. Rhodocenium Functionalization Enabled by Half-Sandwich Capping,  Zincke-Reaction, Diazoniation and Sandmeyer Chemistry

M. Wiedemair, H. Kopacka, K. Wurst, T. Müller, K. Michele, S. Vanicek, S. Hohloch, B. Bildstein*

Eur. J. Inorg. Chem., 2021, 3305 - 3313.

Link

77. Distinct photodynamic of k-N and k-C pseudiisomeric iron(II) complexes

P. Dierks, A. Kruse, O.S. Bokareva, M.J. Al-Marri, M. Baltrun, A. Neuba, R. Schoch, S. Hohloch, K. Heinze, O. Kühn, S. Lochbrunner, M. Bauer*

Chem. Commun., 2021, 57, 6640 - 6643.

Link

76. Bright Luminescent Alkali Metal Carbene Complexes

P. Pinter, C.M. Schüßlbauer, F.A. Watt, N. Dickmann, R. Herbst-Irmer, A. Grünwald, T. Ullrich, M. Zimmer, D.M. Guldi,* S. Hohloch,* D. Munz*

Chem. Sci., 2021, 12, 7401 - 7410.

Link

highlighted by Chemistry Views

highlighted among the most popular 2021 physical and theoretical chemistry articles

75. Amidinate Supporting Ligands Influence Molecularity in Formation of Uranium Nitrides

M.D. Straub, L.M. Moreau, Y. Qioa, E.T. Ouellette, M.A. Boreen, T.D. Lohrey, N.S. Settineri, S. Hohloch, C.H. Booth, S.G. Minasian, J. Arnold*

Inorg. Chem., 2021, 60, 6672 - 6679.

Link

74. eta-3-Coordination and Functionalization of the 2-Phosphaethynthiolate Anion at Lanthanum(III) 

F.A. Watt, L. Burkhardt, R. Schoch, S. Mitzinger, M. Bauer, F. Weigend,* J.M. Goicoechea,* F. Tambornino,* S. Hohloch,*

Angew. Chem. Int. Ed., 2021, 60, 9534 - 9539.

Link

73. Catalytic Deoxygenation of Nitroarenes mediated by high-valent molybdenum(VI)-NHC complexes

S. Liu, J.I. Amaro-Estrada, M. Baltrun, I. Douair, R. Schoch, L. Maron,* S. Hohloch*

Organometallics, 2021, 40, 107 - 118.

Link

72. A Transient Lanthanum Phosphinidene

F.A. Watt, K.N. McCabe, R. Schoch, L. Maron*, S.Hohloch*

Chem. Commun., 2020, 56, 15410 - 15413. 

Link

71. Isocyanate Insertion into a La–P Phosphide Bond: A Versatile Route to Phosphaureate Bridged Heterobimetallic Lanthanide ‒ Coinage Metal Complexes

F.A. Watt, N. Dickmann, R. Schoch, S. Hohloch*

Inorg. Chem., 2020, 59, 13621 - 13631.

Link

70. Reaction of Isocyanide with Uranium(III) Metallocenium Salt Yields Mono- and Dicationic Uranium(IV) products

M.A. Boreen, O.A. Groß, S. Hohloch*, J. Arnold*

Dalton Trans., 2020, 49, 11971 - 11977.

Link

69. Molybdenum(VI) Bis-Imido Complexes of Dipyrromethene Ligands

J. Locher, F.A. Watt, A.G. Neuba, R. Schoch, D. Munz*, S.Hohloch*

Inorg. Chem., 2020, 59, 9847 - 9856.

Link

68. Structure and magnetism of a tetrahedral uranium(III) beta-diketiminate complex

M.A. Boreen, C.A. Gould, C.H. Booth, S. Hohloch*, J. Arnold*

Dalton Trans., 2020, 49, 7938 - 7944.

Link

67. Comparative Studies of Bulky Uranium Metallocene Azides, Isocyanates, and their Borane-Capped Lewis Adducts

M.A. Boreen, K.N. McCabe, T.D. Lohrey, F.A. Watt, L. Maron, S.Hohloch*, J. Arnold*

Inorg. Chem., 2020, 59, 8580 - 8588.

Link

66. Lewis acid capping or a uranium(V) nitride via a uranium(III) azide molecular square

M.A. Boreen, G. Rao, D.G. Villarreal, F.A. Watt, R.D. Britt, S. Hohloch*, J. Arnold*

Chem. Commun., 2020, 56, 4535 - 4538.

Link

65. Monoanionic anilidophosphine ligands in lanthanide chemistry: Scope and Stability

F.A. Watt, A. Krishna, G. Golovanov, H. Ott, R. Schoch, C. Wölper, A.G. Neuba, S. Hohloch*

Inorg. Chem., 2020, 59, 2719 - 2732.

Link

highlighted in ChemistryViews

64. Tuning Pt(II)-Based Donor-Acceptor Systems Through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, Vis-NIR Absorptions Electrochromism and Photocatalysis

S. Sobottka, M. Nößler, A.L. Ostericher, G. Hermann, N.Z. Subat, J. Beerhues,M. Behr-van der Meer, L. Suntrup, U. Albold, S. Hohloch, J.-C. Tremblay, B. Sarkar*

Chem. Eur. J., 2020, 26, 1314 - 1327.

Link

63. Structural, Electrochemical, and Magnetic Studies of Bulky Uranium(III) and Uranium(IV) Metallocenes

M.A. Boreen, D.J. Lussier, B.A. Skeel, T.D. Lohrey, F.A. Watt, D.K. Shuh, J.R. Long, S. Hohloch*, J. Arnold*

Inorg. Chem., 2019, 58,  16629 - 16641.

Link

62. Half-Sandwich Ir(III) and Os(II) Complexes of Pyridyl-Mesoionic Carbenes as Potential Anticancer Agents

J. Kralj, A. Bolje, D.S. Polančec, I. Steiner, T. Gržan, A. Tupek, N. Stojanović, S. Hohloch, D. Urankar, M. Osmak, B. Sarkar,* A. Brozovic,* J. Košmrlj*

Organometallics, 2019, 38, 4082 - 4092. 

Link

61. Di-oxo, oxo-imido and bis-imido-Molybdenum(VI) Complexes with a bis-phenolate-NHC ligand

M. Baltrun, F.A. Watt, R. Schoch, S. Hohloch*

Organometallics, 2019, 38, 3719 – 3729 

Link

60. A New Bis-phenolate Mesoionic Carbene Ligand for Early Transition Metal Chemistry

M. Baltrun, F.A. Watt, R. Schoch, C. Wölper, A.G. Neuba, S. Hohloch*

Dalton Trans., 2019, 48, 14611 – 14625.

Link

59. Isolation of a TMTAA-Based Radical in Uranium bis-TMTAA Complexes

S. Hohloch*, M.E. Garner, C.H. Booth, C.A. Gould, D.J. Lussier, L. Maron*, J. Arnold*

Angew. Chem. Int. Ed., 2018, 57, 16136 – 16140.

Link

58. Homoleptic U(III) and U(IV) amidate complexes

M.D. Straub, S. Hohloch, J. Arnold*

Dalton Trans., 2018, 47, 1772 – 1776. 

Link

57. Interactions of Vanadium(IV) with Amidoxime Ligands: Redox Reactivity

B.F. Parker, S. Hohloch, J.R. Pankhurst, Z. Zhang, J.B. Love, J. Arnold,* L. Rao*

Dalton Trans., 2018, 47, 5695 - 5702.

Link

56. f-Block complexes of a m-terphenyl dithiocarboxylate ligand

M.A. Boreen, B.F. Parker, S. Hohloch, B.A. Skeel, J. Arnold*

Dalton Trans., 2018, 47, 96 - 104.

Link

55. Synthesis, Characterization, and epoxide ring opening reactivity of Thorium-NHC-bpy complexes

M.E. Garner, T.D. Lohrey, S. Hohloch, J. Arnold*

J. Organomet. Chem., 2018, 857, 10 - 15.

Link

54. New supporting ligands in actinide chemistry: Tetramethyltetraazaannulene complexes with thorium and uranium

S. Hohloch, M.E. Garner, B.F. Parker, J. Arnold*

Dalton Trans., 2017, 46, 13768 - 13782.

Link

53. Thorium metallacycle facilitates catalytic alkyne hydrophosphination

M.E. Garner, B.F. Parker, S. Hohloch, R.G. Bergman,* J. Arnold*

J. Am. Chem. Soc., 2017, 139, 12935 - 12938.

Link

52. Benzoquinonoid-bridged dinuclear actinide complexes

S. Hohloch, J.R. Pankhurst, E.E. Jaekel, B.F. Parker, D.J. Lussier, M.E. Garner, C.H. Booth, J.B. Love, J. Arnold*

Dalton Trans., 2017, 46, 11615 - 11625.

Link

51. Hydride Oxidation from a Titanium-Aluminum Bimetallic: Thermal, Electrochemical and Insertion Reactivity

A.C. Brown, A.B. Altman, T.D. Lohrey, S. Hohloch, J. Arnold*

Chem. Sci, 2017, 8, 5153 - 5160.

Link

50. Tuning Magnetic Anisotropy Through Ligand Substitution in Five-Coordinate Co(II) Complexes

D. Schweinfurth, J. Krzystek, M. Antanasov, J. Klein, S. Hohloch, J. Telser,* S. Demeshko, F. Meyer, F. Neese,* B. Sarkar*

Inorg. Chem., 2017, 56, 5253 - 5265.

Link

49. Structural, Electrochemical and Photochemical Properties of Mono and Digold(I) Complexes Containing Mesoionic Carbenes

L. Hettmanczyk, S. Spall, S. Klenk, M. van der Meer, S. Hohloch, J. Weinstein, B. Sarkar*

Eur. J. Inorg. Chem., 2017, 2112 - 2121.

Link

48. Phosphinines versus Mesoionic Carbenes: A Comparison of Structurally Related Ligands in Au(I)-Catalysis

M. Rigo, L. Hettmanczyk, F.J.L. Heutz, S. Hohloch, M. Lutz, B. Sarkar,* C. Müller*

Dalton Trans., 2017, 46, 86 - 95.

Link

47. Control of Complex Formation through Peripheral Substituents in Click-Tripodal Ligands: Structural Diversity in Homo-and Heteronuclear Cobalt-Azido Complexes

M.G. Sommer, R. Marx, D. Schweinfurth, Y. Rechkemmer, P. Neugebaur, M. van der Meer, S. Hohloch, S. Demeshko, F. Meyer, J. van Slageren,* B. Sarkar*

Inorg. Chem., 2017, 56, 402 - 413.

Link

46. The Synthesis and Characterization of Novel Palladium(ii) Acetylacetonate Complexes with Mesoionic Carbenes and their Application in the Suzuki–Miyaura Cross Coupling Reaction

L. Hettmanczyk, B. Schmid, S. Hohloch, B. Sarkar*

Molecules, 2016, 21, 1561/1 - 13.

Link

45. Control of Clustering Behavior in Anionic Lanthanide(III) Corrole Complexes: From Oligomers to Monomers

K.C. Armstrong, S. Hohloch, T.D. Lohrey, R.A. Zarkesh, J. Arnold,* M.R. Anstey*

Dalton Trans., 2016, 45, 18653 - 18660.

Link

44. Expanding the Scope of Chelating Triazolylidenes: Mesoionic Carbenes from the 1,5-“Click”-Regioisomer and Catalytic Synthesis of Secondary Amines from Nitroarenes

L. Suntrup, S. Hohloch, B. Sarkar*

Chem. Eur. J., 2016, 22, 18009 - 18018.

Link

43. Structural Snapshots in the Copper(II) Induced Azide-Nitrile Cycloaddition: Effect of Peripheral Ligand Substituents on the Formation of Unsupported µ1,1-Azido vs. µ1,4-Tetrazolato Bridged Complexes

M.G. Sommer, Y. Rechkemmer, L. Suntrup, S. Hohloch, M. van der Meer, J. van Slageren,* B. Sarkar*

Dalton Trans., 2016, 45, 17770 - 17781.

Link

42. Carbon-Nitrogen bonds cleavageby a Thorium-NHC-bpy Complex

M.E. Garner, S. Hohloch, L. Maron,* J. Arnold*

Angew. Chem. Int. Ed., 2016, 55, 13789 - 13792.

Link

41. A Dicobalt Complex with an Unsymmetrical Quinonoid Bridge Isolated in Three Units of Charge: A Combined Structural, (Spectro)electrochemical, Magnetic and Spectroscopic Study

M. van der Meer, Y. Rechkemmer, U. Frank, F.D. Breitgoff, S. Hohloch, C.-Y, Su, P. Neugebauer, R. Marx, M. Dörfel, J. van Slageren,* B. Sarkar*

Chem. Eur. J., 2016, 22, 13884 - 13893.

Link

40. A new supporting ligand in actinide chemistry leads to reactive bis(NHC)borate-supported thorium complexes

M.E. Garner, S. Hohloch, L. Maron,* J. Arnold*

Organometallics, 2016, 35, 2915 - 2922.

Link

39. Ru II, Ir III and Os II mesoionic carbene complexes: efficient catalysts for transfer hydrogenation of selected functionalities

A. Bolje, S. Hohloch, J. Košmrlj,* B. Sarkar*

Dalton Trans., 2016, 45, 15983 – 15993.

Link

38. Group 5 chemistry supported by β-diketiminate ligands

S. Hohloch, B.M. Kriegel, R.G. Bergman,* J. Arnold*

Dalton Trans., 2016, 45, 15725 – 15745.

Link

37. Exploring Potential Cooperative Effects in Di-Copper-Di-Mesoionic Carbene Complexes

S. Hohloch, L. Suntrup, B. Sarkar*

Inorg. Chem. Front., 2016, 3, 67 - 77.

Link

36. PEPPSI Type Complexes Bearing Mesoionic Carbene Ligands: Applications in α-Arylation, α-Methylation and Suzuki-Miyaura Coupling Reactions

A. Verma, R. Maity, M. van der Meer, S. Hohloch, B. Sarkar*

Eur. J. Inorg. Chem., 2016, 111 - 117.

Link

35. Utilizing a series of fac-Re(CO) 3 core based quinonoid containing complexes for photophysical and cell imaging studies

D. Gupta, V. Singh, S. Hohloch, M. Sathiyendiren,* K. Tedin, B. Sarkar*

Polyhedron, 2015, 100, 243 - 250.

Link

34. Di- and Trinuclear Iridium(III) Complexes with Poly-Mesoionic Carbenes Synthesized Through Selective Base-Dependent Metalation

R. Maity, M. van der Meer, S. Hohloch, B. Sarkar*

Organometalllics, 2015, 34, 3090 - 3096.

Link

33. Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: Electrochemical properties and electronic structures

L. Hettmanczyk, S. Manck, S. Hohloch, M. van der Meer, B. Sarkar*

Chem. Commun., 2015, 51, 10949 – 10952.

Link

32. Tuning Ligand Effects and Probing the Inner-Workings of Bond Activation Steps: Generation of Ruthenium Complexes with Tailor-made Properties

F. Weisser, S. Plebst, S. Hohloch, M. van der Meer, F. Führer, V. Radtke, D. Leichnitz, B. Sarkar*

Inorg. Chem., 2015, 54, 4621 - 4635.

Link

31. Tailoring Ru II Pyridine/Triazole Oxygenation Catalysts and Using Photoreactivity to Probe Electronic Properties

F. Weisser, H. Stevens, J. Klein, M. van der Meer, S. Hohloch, B. Sarkar*

Chem. Eur. J., 2015, 21, 8926 - 8938.

Link

30. Copper(I) Complexes of Mesoionic Carbene: Structural Characterization and Catalytic Hydrosilylation Reactions

S. Hohloch, F.L. Duecker, M. van der Meer, B. Sarkar*

Molecules, 2015, 20, 7379 - 7395.

Link

29. Ru II, Os II, and Ir III Complexes with Chelating Pyridyl–Mesoionic Carbene Ligands: Structural Characterization and Applications in Transfer Hydrogenation Catalysis

A. Bolje, S. Hohloch, M. van der Meer, J. Košmrlj,* B. Sarkar*

Chem. Eur. J., 2015, 21, 6756 - 6764

Link

28. The Ligand Field of the Azido Ligand: Insights into Bonding Parameters and Magnetic Anisotropy in a Co(II)-Azido Complex

D. Schweinfurth, M.G. Sommer, M. Atanosov,* S. Demeshko, S. Hohloch, F. Meyer, F. Neese,* B. Sarkar*

J. Am. Chem. Soc., 2015, 137, 1993 - 2005.

Link

27. Catalytic oxygenation of sp 3 “C–H” bonds with Ir(III) complexes of chelating triazoles and mesoionic carbenes

S. Hohloch, S. Kaiser, F.L. Duecker, A. Bolje, R. Maity, J. Košmrlj, B. Sarkar*

Dalton Trans., 2015, 44, 686 - 693.

Link

26. Spin Crossover in Fe(II) and Co(II) Complexes with the same Click-Derived Tripodal Ligand

D. Schweinfurth, S. Demeshko, S. Hohloch, M. Steinmetz, J. Brandenburg, S. Dechert, F. Meyer, S. Grimme,* B. Sarkar*

Inorg. Chem., 2014, 53, 8203 - 8212.

Link

25. Three-way Cooperativity in d8 Metal Complexes with Ligands Displaying Chemical and Redox Non-Innocence

N. Deibel, S. Hohloch, D. Schweinfurth, F. Weisser, A. Grupp, B. Sarkar*

Chem. Eur. J., 2014, 20, 15178 - 15187.

Link

24. (Electro)catalytic C-C bond formation reaction with a redox-active cobalt complex

M. van der Meer, Y. Rechkemmer, I. Peremykin, S. Hohloch, J. van Slageren,* B. Sarkar*

Chem. Commun., 2014, 50, 11104 – 11106 (invited article for the special issue “Non-innocent Ligands”, highlighted as back cover).

Link

23. Cyclometallated Mono- and Dinuclear Ir(III) Complexes with „Click" Derived Triazoles and Mesoionic Carbenes

R. Maity, S. Hohloch, M. van der Meer, B. Sarkar*

Chem. Eur. J., 2014, 20, 9952 - 9961

Link

22. Dinuclear Quinonoid Bridged d 8 Metal Complexes with Redox-Active Azobenzene Stoppers: Electrochemical Properties and Electrochromic Behavior

N. Deibel, M.G. Sommer, S. Hohloch, J. Schwan, D. Schweinfurth, F. Ehret, B. Sarkar*

Organometallics, 2014, 33, 4756 - 4765. (invited article for the special issue „Organometallic Electrochemistry“).

Link

21. The redox series [Ru(bpy) 2(L)] n, n = +3, +2, +1, 0, with L = bipyridine, “click” derived pyridyl-triazole or bis-triazole: A combined structural, electrochemical, spectro-electrochemical and DFT investigation

S. Hohloch, D. Schweinfurth, M.G. Sommer, F. Weisser, N. Deibel, F. Ehret, B. Sarkar*

Dalton Trans., 2014, 43, 4437 - 4450. (New Talent Europe Themed Issue)

Link

20. Redox-Induced Spin State Switching and Mixed-Valency in Quinonoid Bridged Dicobalt Complexes

D. Schweinfurth, Y. Rechkemmer, S. Hohloch, N. Deibel, I. Peremykin, J. Fiedler, R. Marx, P. Neugebauer, J. van Slageren,* B Sarkar*

Chem. Eur. J., 2014, 20, 3475 - 3486.

Link

19. Introducing potential hemilability into „click“ triazoles and triazolylidenes: Synthesis and Characterization of d 6-metal complexes and oxidations catalysis

S. Hohloch, L. Hettmanczyk, B. Sarkar*

Eur. J. Inorg. Chem., 2014, 3164 - 3171.
(one of the 20 most accessed articles of Eur. J. Inorg. Chem. between 06/2014 and 07/2015).

Link

18. Exploring the scope of 1,2,3-triazol-5-ylidene framework that contains chelating pyridyl-donor ligands in bidentate coordination to (p-cymene)ruthenium(II) chloride complexes

A. Bolje, S. Hohloch, D. Urankar, A. Pevec, M. Gazvoda, B. Sarkar, J. Košmrlj*

Organometallics, 2014, 33, 2588 - 2598.

Link

17. Structural Characterization, Solution Dynamics and Catalytic Properties of Palladium Complexes with Benzimidazolin-2-Ylidene Ligands

S. Hohloch, N. Deibel, D. Schweinfurth, W. Frey, B. Sarkar*

Eur. J. Inorg. Chem., 2014, 2131 - 2139.

Link

16. Electrochemistry, Chemical Reactivity, and Time-resolved IR Spectroscopy of Donor-Acceptor Systems [(Q x)Pt(pap y)] (Q = substituted o-Quinone or o-Iminoquinone, pap = Phenylazopyridine)

N. Deibel, D. Schweinfurth, S. Hohloch, M. Delor, M. Towrie, I. Sazanovich, J. Weinstein,* B. Sarkar*

Inorg. Chem., 2014, 53, 1021 - 1031.

Link

15. Ruthenium Complexes of Tripodal Ligands with Pyridine and Triazole Arms – Subtle Tuning of Thermal, Electro-chemical, and Photochemical Reactivity

F. Weisser, S. Hohloch, S. Plebst, D. Schweinfurth, B. Sarkar*

Chem. Eur. J., 2014, 20, 781 – 793 (highlighted on the inside front cover).

Link

14. Arene–Ruthenium(II) and −Iridium(III) Complexes with “Click”-Based Pyridyl-triazoles, Bis-triazoles, and Chelating Abnormal Carbenes: Applications in Catalytic Transfer Hydrogenation of Nitrobenzene

S. Hohloch, L. Suntrup, B. Sarkar*

Organometallics, 2013, 24, 7376 - 7385.

Link

13. Electrochromic Pt(II) Complexes Derived from Azobenzene and Zwitterionic Quinonoid Ligands: Electronic and Geometric Structures.

N. Deibel, S. Hohloch, M.G. Sommer, D. Schweinfurth, F. Ehret, P. Braunstein, B. Sarkar*

Organometallics, 2013, 32, 7366 – 7375. 

Link

12. Tuning Spin-Spin Coupling in Quinonoid-Bridged Dicopper(II) Complexes with Rational Bridge Variation

D. Schweinfurth, M.M. Khusniyarov,* D. Bubrin, S. Hohloch, C.-Y. Su, B. Sarkar*

Inorg. Chem., 2013, 52, 10332 - 10339. 

Link

11. Redox-Active Triazolium-Derived Ligands in Nucleophilic Fe-Catalysis - Reactivity Profile and Develop-ment of a Regioselective O-Allylation

J.E.M.N. Klein, M.S. Holzwarth, S. Hohloch, B. Sarkar,* B. Plietker*

Eur. J. Org. Chem., 2013, 6310 - 6316.

Link

10. Abnormal Carbenes derived from the 1,5-cycloaddition product between azides and alkynes: structural characterization of Pd(II) complexes and their catalytic properties

S. Hohloch, W. Frey, C.-Y. Su, B. Sarkar*

Dalton Trans., 2013, 42, 11355 – 11358 (selected as hot article, highlighted on inside front cover)

Link

9. Influencing the coordination mode of TBTA (TBTA = Tri[(1-benzyl-1H-1,2,3-triazol4-yl)methyl]amine) in dicobalt complexes through changes in metal oxidation states

D. Schweinfurth, J. Klein, S. Hohloch, S. Dechert, S. Demeshko, F. Meyer, B. Sarkar*

Dalton Trans., 2013, 42, 6944 - 6952.

Link

8. Activating Azides and Alkynes for the Click reaction with [Cu(aNHC) 2I] or [Cu(aNHC) 2] + (aNHC = triazol-derived abnormal carbenes): Structural characterization and catalytic properties

S. Hohloch, D. Scheiffele, B. Sarkar*

Eur. J. Inorg. Chem., 2013, 22 – 23, 3956 - 3965. (invited article for a special issue “Small Molecule Activation with Reactive Metal Complexes”)

Link

7. Substituent induced Reactivity in Quinoid bridged dinuclear complexes: Comparison between the Ruthenium and the Osmium systems

M.G. Sommer, D. Schweinfurth, F. Weisser, S. Hohloch, B. Sarkar*

Organometallics, 2013, 32, 2069 - 2078.

Link

6. Hetero-bimetallic Cu-dppf (dppf = 1,1'-Bis(diphenylphosphino)ferrocene) Complexes with "Click" Derived Ligands: A Combined Structural, Electrochemical, Spectroelectrochemical, and Theoretical Study

D. Schweinfurth, N. Buettner, S. Hohloch, N. Deibel, J. Klein, B. Sarkar*

Organometallics, 2013, 32, 5834 - 5842. (invited article for the special issue „Ferrocene: Beauty and Function“)

Link

5. Are Cu(I)-mesoionic NHC carbenes associated with nitrogen additives the best Cu-carbene catalysts for the azide-alkyne click reaction so far? A case study

S. Hohloch, B. Sarkar,* L. Nauton, F. Cisnetti, A. Gautier*

Tetrahedron Lett., 2013, 54, 1808 - 1812. 

Link

4. Ruthenium Hydride Complexes with Zwitter-ionic Quinonoid Ligands - Isomer Separation, Structural Properties, Electrochemistry, and Catalysis

S. Hohloch, P. Braunstein, B. Sarkar*

Eur. J. Inorg. Chem., 2012, 3, 546 - 553. (invited article for a special issue Cooperative and Redox Non-Innocent Ligands)

Link

3. Donor-acceptor systems of Pt(II) and electron transfer induced reactivity

N. Deibel, D. Schweinfurth, S. Hohloch, J. Fiedler, B. Sarkar*

Chem. Commun., 2012, 48, 2388 – 2390 (highlighted on the inside front cover).

Link

2. Characterization of [Pd(pap)(NHC)I2]n (n = +1, 0, -1; pap = Phenylazopyridine; NHC = N-Heterocyclic Carbene): Unusual Coordination Mode of pap and Non-innocent Behavior of NHC

N. Deibel, D. Schweinfurth, S. Hohloch, B. Sarkar*

Inorg. Chim. Acta, 2012, 380, 269 - 273. (young investigator issue).

Link

1. Copper(I) complexes of normal and abnormal carbenes and their use as catalysts for the Huisgen [3+2] cycloaddition between azides and alkynes

S. Hohloch, C.-Y. Su, B. Sarkar*

Eur. J. Inorg. Chem., 2011, 20, 3067 - 3075. (belonged to the most cited papers in 2011 and 2012)

Link

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