University of Innsbruck


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Peer-Reviewed Publications   Patents   Editorials   PhD Thesis

Peer-Reviewed Publications

54. Crystalline phosphino(silyl)carbenes that readily form transition metal complexes
P. Löwe, F. Dielmann*
Chem. Commun. 2022, 58, 11831-11834; Link


53. Solvent-free photochemical decomposition of sulfur hexafluoride by phosphines: formation of difluorophosphoranes as versatile fluorination reagents
P. Rotering, C. Mück-Lichtenfeld, F. Dielmann*
Green Chem. 2022, 24, 8054-8061; Link

52. Reactivity of oxo- and thiophosphonium Lewis acids towards acetonitrile and pyridine
T.N. Parfeniuk, I.V. Kazakov, A.V. Pomogaeva, A.S. Lisovenko, P. Lӧwe, F. Dielmann, A.Y. Timoshkin*
Polyhedron 2022, 227, 116138; Link


51. Oxidative Fluorination of Selenium and Tellurium Compounds using a Thermally Stable Phosphonium SF5- Salt Accessible from SF6
T. Eder, F. Buß, L. F. B. Wilm, M. Seidl, M. Podewitz, F. Dielmann*
Angew. Chem. Int. Ed. 2022, 61, e202209067; Link


50. Synthesis of N-Heterocyclic Carbenes and Their Complexes by Chloronium Ion Abstraction from 2-Chloroazolium Salts Using Electron-Rich Phosphines
M. D. Böhme, T. Eder, M. B. Röthel, P. D. Dutschke, L. F. B. Wilm, F. E. Hahn,* F. Dielmann*
Angew. Chem. Int. Ed. 2022, 61, e20220219; Link


49. Photoswitchable Nitrogen Superbases: Using Light for Reversible Carbon Dioxide Capture
L. F. B. Wilm, M. Das, D. Janssen-Müller, C. Mück-Lichtenfeld, F. Glorius,* F. Dielmann*
Angew. Chem. Int. Ed. 2022, 61, e202112344; Link
Frontispiece: LinkLink
Highlight: Link


48. Tris(tetramethylguanidinyl)phosphine: The simplest non-ionic phosphorus superbase and strongly-donating phosphine ligand
F. Buß, M. B. Röthel, J. A. Werra, P. Rotering, L. F. B. Wilm, C. G. Daniliuc, F. Dielmann*
Chem. Eur. J. 2022, 28, e20210402; Link


47. Multistimuli-Responsive [3]Dioxaphosphaferrocenophanes with Orthogonal Switches
B. S. Birenheide, F. Krämer, L. Bayer, P. Mehlmann, F. Dielmann,* F. Breher*
Chem. Eur. J. 2021, 27, 15067–15074; Link
Cover Feature: Link


46. Thiophosphonium-Alkyne Cycloaddition Reactions: A Heavy Congener of the Carbonyl Alkyne Metathesis
P. Löwe, M. Feldt, M. B. Röthel, L. F. B. Wilm, F. Dielmann*
Inorg. Chem.2021, 60, 14509-14514; Link


45. Lewis base-free thiophosphonium ion: a cationic sulfur atom transfer reagent
P. Löwe, T. Witteler, F. Dielmann*
Chem. Commun.2021, 57, 5043-5046; Link


44. Heterobimetallic complexes composed of bismuth and lithium carboxylates as polyurethane catalysts – alternatives to organotin compounds
E. Levent, O. Sala, L. F.B. Wilm, P. Löwe, F. Dielmann*
Green Chem. 2021, 23, 2747-2755; Link


43. Electroreduction of CO2 catalyzed by nickel imidazolin-2-ylidenamino-porphyrins in both heterogeneous and homogeneous molecular systems
M. Abdinejad, L. F. B. Wilm, F. Dielmann,* H. B. Kraatz*
ACS Sustainable Chem. Eng. 2021, 9, 521-530; Link


42. Oxophosphonium−Alkyne Cycloaddition Reactions: Reversible Formation of 1,2 Oxaphosphetes and Six-membered Phosphorus Heterocycles
P. Löwe, M. Feldt, M. A. Wünsche, L. F. B. Wilm, F. Dielmann*
J. Am. Chem. Soc. 2020, 142, 9818-9826; Link


41. Effective control of the electron-donating ability of phosphines by using phosphazenyl and phosphoniumylidyl substituents
J. A. Werra, M. A. Wünsche, P. Rathmann, P. Mehlmann, P. Löwe, F. Dielmann*
Z. Anorg. Allg. Chem.2020, 646, 794-799; Link


40. Synthesis and characterization of strongly electron-donating bidentate phosphines containing imidazolin-2-ylidenamino substituents and their electron-rich nickel(0), palladium(II) and gold(I) chelate complexes
L. F. B. Wilm, P. Mehlmann, F. Buß, F. Dielmann*
J. Organomet. Chem. 2020, 909, 1-8; Link


39. Enhanced Electrochemical Reduction of CO2 to CO upon Immobilization onto Carbon Nanotubes Using an Iron-Porphyrin Dimer
M. Abdinejad, C. Dao, B. Deng, M. E. Sweeney, F. Dielmann,* X. Zhang,* H. B. Kraatz*
ChemistrySelect 2020, 5, 979-984; Link


38. Pyridinylidenaminophosphines: Facile Access to Highly Electron-Rich Phosphines
P. Rotering, L. F. B. Wilm, J. A. Werra, F. Dielmann*
Chem. Eur. J.2020, 26, 406-411; Link


37.  A general pathway to heterobimetallic triple-decker complexes
M. Piesch, F. Dielmann, S.Reichl, M. Scheer*
Chem. Eur. J. 2020, 26, 1518-1524; Link


36. Cooperative activation of azides by an Al/N-based active Lewis pair – unexpected insertion of nitrogen atoms into C–Si bonds and formation of AlCN3 heterocycles
W. Uhl,* K. Martinewski, J. Silissa Bruchhage, A. Hepp, M. Layh, F. Dielmann, P. Mehlmann
Z. Naturforsch.2020, 75b, 63-71; Link


35. Isolation, characterization and reactivity of three-coordinate phosphorus dications isoelectronic to alanes and silylium cations
P.l Mehlmann, T. Witteler, L. F. B. Wilm, F. Dielmann*
Nat. Chem. 2019, 11, 1139-1143; Link


34. Homo- and Heterodinuclear Head-to-Head or Head-to-Tail Complexes of Rhodium(I) and Iridium(I) with C2,N3 or C8,N9 Bridging Azolato Ligands
S. Cepa, M. Böhmer, F. Roelfes, T. Tsai Yuan Tan, F. Dielmann, F. E. Hahn*
Organometallics 2019, 38, 1982-1990; Link


33. Reversible CO2 fixation by N-heterocyclic imines forming water-stable zwitterionic nitrogen-base–CO2 adducts
L. F. B. Wilm, T. Eder, C. Mück-Lichtenfeld, P.Mehlmann, M. Wünsche, F. Buß, F. Dielmann*
Green. Chem., 2019, 21, 640; Link


32. Switching the Electron-Donating Ability of Phosphines via Proton-Responsive Imidazolin-2 ylidenamino Substituents
P. Mehlmann, F. Dielmann*
Chem. Eur. J. 2019, 25, 2352-2357; Link


31. Dialkyl(1,3-diarylimidazolin-2-ylidenamino)phosphines: Strongly Electron-Donating, Buchwald-type Phosphines
T. Witteler, H. Darmandeh, P.Mehlmann, F. Dielmann*
Organometallics2018, 37, 3064-3072; Link


30. Crystalline, Room-Temperature Stable Phosphine‒SO2 Adducts: Generation of Sulfur Monoxide from Sulfur Dioxide
F. Buß, P. Rotering, Ch. Mück-Lichtenfeld, F. Dielmann*
Dalton Trans.2018, 47, 10420-10424; Link


29. Lewis Base Free Oxophosphonium Ions: Tunable, Trigonal-planar Lewis Acids
M. Wünsche, T. Witteler, F. Dielmann*
Angew. Chem. Int. Ed. 2018, 57, 7234-7239; Angew. Chem. 2018, 130, 7354-7359; Link


28. Nucleophilic Activation of Sulfur Hexafluoride: Metal-free, Selective Degradation by Phosphines
F. Buß, Ch. Mück-Lichtenfeld, P. Mehlmann, F. Dielmann*
Angew. Chem. Int. Ed. 2018, 57, 4951-4955; Angew. Chem.2018, 130, 5045-5049; Link


27. Stable Bromiranium Ions with Weakly-Coordinating Counterions as Efficient Electrophilic Brominating Agents
Ch. Ascheberg, J. Bock, F. Buß, Ch. Mück-Lichtenfeld, C. G. Daniliuc, K. Bergander, F. Dielmann, U. Hennecke*
Chem. Eur. J. 2017, 23, 11578–11586; Link


26. A tri-arylated 1,2,3-triazol-5-ylidene ligand with a redox-active ferrocenyl substituent for rhodium(I) catalyzed hydroformylation of 1-octene
D. Aucamp, T. Witteler, F. Dielmann, S. Siangwata, D. C. Liles, G. S. Smith, D. I. Bezuidenhout*
Eur. J. Inorg. Chem. 2017, 1227-1236; Link


25. Quantifying the Efficiency of CO2 Capture by Lewis Pairs
J. J. Chi, T. C. Johnstone, D. Voicu, P. Mehlmann, F. Dielmann, E. Kumacheva,* D. W. Stephan*
Chem. Sci.2017, 8, 3270-3275; Link


24. Tris(imidazolin-2-ylidenamino)phosphine: A crystalline phosphorus(III) superbase that splits carbon dioxide
P. Mehlmann, Ch. Mück-Lichtenfeld, T. T. Y. Tan, F. Dielmann*
Chem. Eur. J. 2017, 23, 5929-5933; Link


23. The Cobalt cyclo-P4 Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds
F. Dielmann, A. Timoshkin, M. Piesch, G. Balázs, M. Scheer*
Angew. Chem. Int. Ed. 2017, 56, 1671-1675; Angew. Chem. 2017, 129, 1693-1698; Link


22. Reversible Carbon Dioxide Binding by Simple Lewis Base Adducts with Electron-Rich Phosphines
F. Buß, P. Mehlmann, Ch. Mück-Lichtenfeld, K. Bergander, F. Dielmann*
J. Am. Chem. Soc.2016, 138, 1840-1843; Link


21. Tetrahedrally coordinated luminescent copper(I) compounds containing halide, phosphane and norharmane ligands
R. Ahmad Khan, F. Dielmann, X. Liu, F. E. Hahn, K. Al-Farhan, A. Alsalme, J. Reedijk*
Polyhedron 2016, 111, 173-178; Link


20. Synthesis, structure and spectroscopic properties of bis(triphenylphosphane)iminium (chlorido)(cyanido)argentates(I)
M. Jaafar, X. Liu, F. Dielmann, F. E.Hahn, K. Al-Farhan, A. Alsalme and J. Reedijk*
Inorg. Chim. Acta 2016, 443, 45-50; Link


19. Cyclo-P4 Building Blocks: Achieving Non-Classical Fullerene Topology and Beyond
F. Dielmann, E. V. Peresypkina, B. Krämer, F. Hastreiter, B. P. Johnson, M. Zabel, C. Heindl, and M. Scheer*
Angew. Chem. Int. Ed. 2016, 55, 14833-14837; Angew. Chem. 2016, 128, 15053-15058; Link


18. Oxidation Chemistry of Inorganic Benzene Complexes
M. Fleischmann, F. Dielmann, G. Balázs and M. Scheer*
Chem. Eur. J. 2016, 22, 15248-15251; Link


17. Synthesis, structure and spectroscopic properties of bis(triphenylphosphane)iminium(phenylacetylido)(cyanido)aurate(I) monoacetone monohydrate, (PPN)[Au(CN)(CCC6H5)]·H2O·(CH3)2CO and bis(triphenylphosphane)iminium (t-butylacetylido)(cyanido)aurate(I) monohydrate, (PPN)[Au(CN)(CCC4H9)]·H2O
A. Alsalme, M. Jaafar, X. Liu, F. Dielmann, F. E. Hahn, K. Al-farhan, J. Reedijk*
Polyhedron 2015, 88, 1-5; Link


16. Imidazolin-2-ylidenaminophosphines as Highly Electron-Rich Ligands for Transition-Metal Catalysts
M. A. Wünsche, P. Mehlmann, T. Witteler, F. Buß, P. Rathmann, F. Dielmann*
Angew. Chem. Int. Ed. 2015, 54, 11857-11860; Angew. Chem. 2015, 127, 12024-12027; Link


15. Reactivity of a Stable Phosphinonitrene towards Small Molecules
F. Dielmann and G.Bertrand*
Chem. Eur. J. 2015, 21, 191−198; Link

14.  Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo)2(,6:6-P6)] Towards the “Naked” Cations Cu+, Ag+, and Tl+
M. Fleischmann, F. Dielmann, L. J. Gregoriades, E. V. Peresypkina, A. V. Virovets, S. Huber, A. Y. Timoshkin, G. Balázs, and M. Scheer*
Angew. Chem. Int. Ed. 2015, 54, 13110-13115; Angew. Chem.2015, 127, 13303-13308; Link

13. Tunable Porosities and Shapes of Fullerene-Like Spheres 
F. Dielmann, M. Fleischmann, C. Heindl, E. V. Peresypkina, A. V. Virovets, R.M. Gschwind, and M. Scheer*
Chem. Eur. J. 2015, 21, 6208−6214; Link

12. Isolation of Bridging and Terminal Coinage Metal-Nitrene Complexes
F. Dielmann, D. M. Andrada, G. Frenking, G. Bertrand*
J. Am. Chem. Soc.2014, 136, 3800−3802; Link

11.  A Nano-sized Supramolecule Beyond the Fullerene Topology
F. Dielmann, C. Heindl, F. Hastreiter, E. V. Peresypkina, A. V. Virovets, R. M. Gschwind, and M. Scheer*
Angew. Chem. Int. Ed. 2014, 53, 13605−13608; Angew. Chem. 2014, 126, 13823−13827; Link

10.  Crystalline, Lewis Base-Free, Cationic Phosphoranimines (Iminophosphonium Salts)
F. Dielmann, C. E. Moore, A. L. Rheingold, G. Bertrand*
J. Am. Chem. Soc. 2013, 135, 14071−14073; Link

9. Intramolecular Phosphorus-Phosphorus Bond Formation within a Co2P4 Core
T. Li, N. Arleth, M. T. Gamer, R. Köppe, T. Augenstein, F. Dielmann, M. Scheer, S.N. Konchenko, P. W. Roesky*
Inorg. Chem. 2013, 52, 14231−14236; Link

8. A Crystalline Singlet Phosphinonitrene: A Nitrogen Atom–Transfer Agent
F. Dielmann, O. Back, M. Henry-Ellinger, P. Jerabek, G. Frenking, G. Bertrand*
Science 2012, 337, 1526−1528; Link

7. Coordination Polymers Based on [Cp*Fe(η5-P5)]: Solid-State Structure and MAS NMR Studies
F. Dielmann, A. Schindler, S. Scheuermayer, J. Bai, R. Merkle, M. Zabel, A. V. Virovets, E. V. Peresypkina, G. Brunklaus, H. Eckert, M. Scheer*
Chem. Eur. J. 2012, 18, 1168−1179; Link

6. Access to Extended Polyphosphorus Frameworks
F. Dielmann, M. Sierka, A. V. Virovets, M. Scheer*
Angew. Chem., Int. Ed. 2010, 49, 6860−6864; Angew. Chem.2010, 122, 7012−7016; Link

5. Synthesis and reactivity of low-valent group 14 element compounds
B. P. Johnson, S. Almstätter, F. Dielmann, M. Bodensteiner, M. Scheer*
Z. Anorg. Allg. Chem. 2010, 636, 1275−1285; Link

4. New pentaphosphaferrocenes
F. Dielmann, R. Merkle, S. Heinl, M. Scheer*
Z. Naturforsch. 2009, 64b, 3−10; Link

3. Dimolybdenum Bis-2,4,6-triisopropyl-benzoate Bis-4-isonicotinate: A Redox Active Analogue of 4,4′-Bipyridine with Ambivalent Properties
M. H. Chisholm, A. S. Dann, F. Dielmann, J. C. Gallucci, N. J. Patmore, R. Ramnauth, M. Scheer*
Inorg. Chem. 2008, 47, 9248−9255; Link

2. Dynamic Investigation on Supramolecular Compounds using Pn ligand complexes
M. Scheer,* L. J. Gregoriades, R.Merkle, B. P. Johnson, F. Dielmann
Phosphorus, Sulfur and Silicon and the Related Elements2008, 183, 504−508; Link

1. Spherical Cluster Comprising a Four- and Six-Membered-Ring Motif
B. P. Johnson, F. Dielmann, G. Balázs, M. Sierka, M.Scheer*
Angew. Chem. Int. Ed. 2006, 45, 2473−2475; Angew. Chem.2006, 118, 2533−2536; Link


9. Methods for decomposing sulfur hexafluoride
F. Dielmann, P. Rotering
European patent application (Nr. EP 21 194 663.7, application date 02.09.2021).

8. Electron-rich carboxylates as ligands for Lewis acidic metal complexes as catalysts in the polyurethane reaction
F. Dielmann, P. Hoffmann, E. Levent
European patent application (Nr. EP 20 189 240.3, application date 03.08.2020)

7. Zinkhaltiger Katalysator umfassend mindestens einen aromatischen Substituenten
F. Dielmann, P. Hoffmann, E. Levent
European patent application (Nr. EP 20 189 240.3, application date 03.08.2020).
PCT Int. Appl. (2022), WO 2022028850 A1 20220210

6. Mixtures comprising bismuth-containing catalysts and diols
F. Dielmann, P. Hoffmann, E. Levent
European patent application (Nr. EP 20 153 336.1, application date 23.01.2020).
PCT Int. Appl. (2021), WO2021148332 A1 20210729.

5. Process to the fluorination of organoelement compounds
F. Buß, F. Dielmann, M. Wünsche
German patent application (Nr. 10 2019 108 416.4, application date 01.04.2019).
Ger. Offen. (2020), DE 102019108416 A1 20201001.

4. Bismuth-containing catalyst comprising at least one aromatic substituent
F. Dielmann, P. Hoffmann, E. Levent
European patent application (Nr. 19155916.0, application date: 07.02.2019).
PCT Int. Appl. (2020), WO 2020160939 A1 20200813.

3. Air cooler
F. Buß, F. Dielmann, M. Wünsche
German patent application (Nr. 10 2017 124 711.4, application date: 23.10.2017).
Ger. Offen. (2019), DE 102017124711 A1 20190425.

2. Methods for the degradation of SF6
F. Buß, F. Dielmann
International patent (No: WO/2019/077086, International application number PCT/EP2018/078652, application date: 19.10.2017).
PCT Int. Appl. (2019), WO 2019077086 A1 20190425.

1. Gasdichter Gewindeansatz und Verschlussstempel für NMR-Rohre
J. Berendes, F. Buß, F. Dielmann, F. Henrichmann, M. Wünsche
German utility model (Nr. 20 2017 004 691, application date: 08.09.2017, Entry date: 15.12.2017).


2. The Organometallic Chemistry of Metal Carbene Complexes
F. Dielmann
J. Organomet. Chem. 2020, 923, 121416; Link

1. In celebration of the 65th birthday of Manfred Scheer
F. Dielmann, R. Kretschmer
Z. Anorg. Allg. Chem. 2020, 646, 545-546; Link

PhD Thesis

Novel phosphorus rich complexes and their use in supramolecular chemistry
Fabian Dielmann (Dissertation)
München: Verlag Dr. Hut, 2011 [ISBN 9783868538946].